5. Results and discussion
5.1. Calculation of solid surface tension and prediction of droplet shape The silver ink droplet shape on a smooth substrate was captured using the Drop Shape Analysis System DSA100. Knowing the characteristics of a droplet, Eq. (9) was solved to predict the asymptotic contact angle, s. Having the asymptotic contact angle and liquidgas surface tension, the solid surface tensions could be calculated from Eq.(8). The solid surface tensions for glass and PTFE substrates were hence determined to be 0.0228 N/m and 0.0043 N/m respectively for the silver ink used. The experimental uncertainty for the measurement of solid surface tensions was estimated to be less than 6%. The solid surface tensions value for the PTFE substrate is relatively low and consequently the silver ink demonstrated poor wettability of the PTFE, resulting in a series of disconnected droplets, as shown in Fig. 4(a). In contrast the relatively high solid surface tensions value with the glass substrate resulted in high wettability of the silver ink, as shown in Fig. 4(b). Fig. 5 compares the experimental data with predicted droplet shape. The latter obtained from solving the system of ordinary differential Eqs.(2)–(5) along with Eq.(9) and the boundary conditions given by Eq. (7), knowing only the droplet volume and physical properties. The percentage of absolute errors between theoretical prediction and experimental data for points 1–8 respectively were 0.79, 0.01, 0.67, 0.49, 0.38, 0.67, 0.61 and 0.4. Point 8 has maximum radius of triple line. The good agreement between experimental data and theoretical prediction indicates the accuracy of Eq. (9).