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دانلود رایگان مقاله مسیرهای مختلف ایجاد تغییر در مونت موریلونیت با نمکهای آمونیوم و فسفونیم

عنوان فارسی: مطالعه مقایسه ای مسیرهای مختلف ایجاد تغییر در مونت موریلونیت با نمکهای آمونیوم و فسفونیم
عنوان انگلیسی: A comparative study of different routes for the modification of montmorillonite with ammonium and phosphonium salts
تعداد صفحات مقاله انگلیسی : 10 تعداد صفحات ترجمه فارسی : ترجمه نشده
سال انتشار : 2016 نشریه : الزویر - Elsevier
فرمت مقاله انگلیسی : PDF کد محصول : E2117
محتوای فایل : PDF حجم فایل : 1 Mb
رشته های مرتبط با این مقاله: شیمی، زمین شناسی
گرایش های مرتبط با این مقاله: شیمی آلی، شیمی معدنی
مجله: علوم کاربردی خاک رس - Applied Clay Science
دانشگاه: دانشکده مهندسی شیمی، دانشگاه ایالتی کمپیناس، آلبرت اینشتین، برزیل
کلمات کلیدی: مونت موریلونیت روند، فوق بحرانی، نیمه جامد، نمک فسفونیم، نمک آمونیوم چهارتایی
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چکیده

abstract

The objective of this work was to use a statistical tool to study and evaluate the main parameters in the preparation of organo-montmorillonite (O-Mt) by using different compounds and reactional routes (aqueous, semi-solid and supercritical CO2 medium) aiming a better relationship between efficiency and environmental impact. For this, ammonium-modified montmorillonite (AmMt) and phosphonium-modified montmorillonite (PhMt) were prepared according to design of experiments. The samples were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) and contact angle. XRD and TGA analysis showed that the compounds were incorporated in the montmorillonite providing an efficient modification by all the reactional routes employed. The clay interlayer spacing was expanded and AmMt showed the largest d001 while PhMt showed better thermal stability. Statistical analysis indicated that the process parameters had low or no significance in the organo-montmorillonite characteristics. XRD, TGA and FTIR showed that the d001, yield and chemical environment of the O-Mt changed with the amount of organic compound and washing process. The contact angle test showed that the surface tension of montmorillonite was reduced with organophilization. It was concluded that semi-solid method could be a good, efficient and environmentally friendly alternative to prepare O-Mt.

نتیجه گیری

4. Conclusions

The functionalization of a montmorillonite with ammonium and phosphonium salt by aqueous, semi-solid and supercritical CO2 medium was confirmed by the results of XRD, FTIR, TGA-DTG and contact angles. It was concluded that the semi-solid method can be suggested as the best alternative since the DOE results to d-value and yield were similar or better than the others methods, and also due to its supposed lower environmental impact as it do not use a large amount of solvent and do not generates high amount of effluents. Furthermore, the process in supercritical CO2 was not effective for modifying clay minerals with phosphonium salt. Ammonium-modified montmorillonite showed larger d-value (about 3.8 nm) than phosphonium-modified montmorillonite (about 2.7 nm), however, the latter showed to be about 100°C more thermal stable. These two compounds present interesting properties to be combined in order to get organo hybrid-modified montmorillonite with high thermal stability and high basal spacing to be used in CPN by a simple and eco-friendly process.